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  1. Abstract Exhumed fault rocks provide a textural and chemical record of how fault zone composition and architecture control coseismic temperature rise and earthquake mechanics. We integrated field, microstructural, and hematite (U-Th)/He (He) thermochronometry analyses of exhumed minor (square-centimeter-scale surface area) hematite fault mirrors that crosscut the ca. 1400 Ma Sandia granite in two localities along the eastern flank of the central Rio Grande rift, New Mexico. We used these data to characterize fault slip textures; evaluate relationships among fault zone composition, thickness, and inferred magnitude of friction-generated heat; and document the timing of fault slip. Hematite fault mirrors are collocated with and crosscut specular hematite veins and hematite-cemented cataclasite. Observed fault mirror microstructures reflect fault reactivation and strain localization within the comparatively weaker hematite relative to the granite. The fault mirror volume of some slip surfaces exhibits polygonal, sintered hematite nanoparticles likely created during coseismic temperature rise. Individual fault mirror hematite He dates range from ca. 97 to 5 Ma, and ~80% of dates from fault mirror volume aliquots with high-temperature crystal morphologies are ca. 25–10 Ma. These aliquots have grain-size–dependent closure temperatures of ~75–108 °C. A new mean apatite He date of 13.6 ± 2.6 Ma from the Sandia granite is consistent with prior low-temperature thermochronometry data and reflects rapid, Miocene rift flank exhumation. Comparisons of thermal history models and hematite He data patterns, together with field and microstructural observations, indicate that seismicity along the fault mirrors at ~2–4 km depth was coeval with rift flank exhumation. The prevalence and distribution of high-temperature hematite grain morphologies on different slip surfaces correspond with thinner deforming zones and higher proportions of quartz and feldspar derived from the granite that impacted the bulk strength of the deforming zone. Thus, these exhumed fault mirrors illustrate how evolving fault material properties reflect but also govern coseismic temperature rise and associated dynamic weakening mechanisms on minor faults at the upper end of the seismogenic zone. 
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  2. Abstract Friction-generated heat and the subsequent thermal evolution control fault material properties and thus strength during the earthquake cycle. We document evidence for transient, nanoscale fault rheology on a high-gloss, light-reflective hematite fault mirror (FM). The FM cuts specularite with minor quartz from the Pleistocene El Laco Fe-ore deposit, northern Chile. Scanning and transmission electron microscopy data reveal that the FM volume comprises a <50-μm-thick zone of polygonal hematite nanocrystals with spherical silica inclusions, rhombohedral twins, no shape or crystallographic preferred orientation, decreasing grain size away from the FM surface, and FM surface magnetite nanoparticles and Fe2+ suboxides. Sub–5-nm-thick silica films encase hematite grains and connect to amorphous interstitial silica. Observations imply that coseismic shear heating (temperature >1000 °C) generated transiently amorphous, intermixed but immiscible, and rheologically weak Fe-oxide and silica. Hematite regrowth in a fault-perpendicular thermal gradient, sintering, twinning, and a topographic network of nanometer-scale ridges from crystals interlocking across the FM surface collectively restrengthened fault material. Results reveal how temperature-induced weakening preconditions fault healing. Nanoscale transformations may promote subsequent strain delocalization and development of off-fault damage. 
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